Breathers and Photoinduced Absorption in Polyacetylene

نویسندگان

  • A. R. Bishop
  • D. K. Campbell
  • P. S. Lomdahl
  • S. R. Phillpot
چکیده

'The dynamics of trans-polyacetylene is studied within the adiabatic model of Su, Schrieffer, and Beeper. A single soliton has a maximum velocity, v, which can be higher than the sound velocity. A long-time simulation shows that, from an initial electron-hole pair, a soliton and antisoliton emerge with velocities +v and that a persistent breather is left behind. 'This breather may account for the high-energy intragap structure observed in photoinduced absorption, including isotope dependence.

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تاریخ انتشار 2011